[μ-1κC1:2(C2,C3-η)-Allyl]tetracarbonyl-1κ2C,2κ2C-(1η5-cyclopentadienyl)(2η5-pentamethylcyclopentadienyl)diiron(II) hexafluorophosphate

Evans O. Changamu; Holger B. Friedrich; M. Rademeyer

doi:10.1107/s1600536806003503

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[μ-1κC¹:2(C²,C³-η)-Allyl]tetracarbonyl-1κ²C,2κ²C-(1η⁵-cyclopentadienyl)(2η⁵-pentamethylcyclopentadienyl)diiron(II) hexafluorophosphate

Evans O. Changamu Holger B. Friedrich M. Rademeyer

Year: 2006 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 62 (3)Pages: m442-m444 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536806003503

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Abstract

In the title molecule, [Fe2(C3H5)(C5H5)(C10H15)(CO)4]PF6, an allyl chain bridges two Fe metal centres, forming a chiral positively charged molecular ion, with hexafluorophosphate as the counterion. In the crystal structure, both enantiomers are present.

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Chemistry Physics Radiochemistry

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[μ-1κC¹:2(C²,C³-η)-Allyl]tetracarbonyl-1κ²C,2κ²C-(1η⁵-cyclopentadienyl)(2η⁵-pentamethylcyclopentadienyl)diiron(II) hexafluorophosphate

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