Pentacarbonyl-1κ4C,2κC-[2(η5)-cyclopentadienyl]-μ-dicyclohexylphosphido-1:2κ2P-manganeserhodium(Mn–-Rh)

Ülrich Flörke; H.‐J. Haupt

doi:10.1107/s0108270199004175

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Pentacarbonyl-1κ⁴C,2κC-[2(η⁵)-cyclopentadienyl]-μ-dicyclohexylphosphido-1:2κ²P-manganeserhodium(Mn–-Rh)

Ülrich Flörke H.‐J. Haupt

Year: 1999 Journal: Acta Crystallographica Section C Crystal Structure Communications Vol: 55 (7)Pages: 1051-1052 Publisher: Wiley

DOI: 10.1107/s0108270199004175

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Abstract

The title compound, [MnRh(C 5 H 5 ){μ-P(C 6 H 11 ) 2 }-(CO) 5 ], is a valence-electron-saturated dinuclear manganese-rhodium cluster compound with an Mn-Rh bond length of 2.763 (1) A.

Keywords:

Cyclopentadienyl complex Chemistry Physics Organic chemistry Catalysis

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Catalytic Cross-Coupling Reactions

Physical Sciences → Chemistry → Organic Chemistry

Asymmetric Hydrogenation and Catalysis

Physical Sciences → Chemistry → Inorganic Chemistry

Pentacarbonyl-1κ⁴C,2κC-[2(η⁵)-cyclopentadienyl]-μ-dicyclohexylphosphido-1:2κ²P-manganeserhodium(Mn–-Rh)

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