Bis(μ-pyridinyl-1-oxide)-1κO1:2κC2;1κC2:2κO1-bis[(η4-cycloocta-1,5-diene)rhodium(I)]

R. Fandos; Marc D. Walter

doi:10.1107/s1600536806000523

ScienceGate Book Chapters

JOURNAL ARTICLE

Bis(μ-pyridinyl-1-oxide)-1κO¹:2κC²;1κC²:2κO¹-bis[(η⁴-cycloocta-1,5-diene)rhodium(I)]

R. Fandos Marc D. Walter

Year: 2006 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 62 (2)Pages: m264-m266 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536806000523

Get Full-Text PDF Get Analytical Report

Abstract

In the title compound, [Rh2(C5H4N)2(C8H12)2], the two rhodium(I) centres are coordinated by one η4-cycloocta-1,5-diene ligand, and by a pyridinyl 1-oxide ortho-C atom from one bridging pyridinyl 1-oxide group and by a pyridinyl 1-oxide O atom from the other. The molecule has approximate C2 symmetry, with the pseudo-C2 axis perpendicular to the Rh⋯Rh vector.

Keywords:

Oxide Chemistry Rhodium Crystallography Atom (system on chip) Ligand (biochemistry) Stereochemistry Medicinal chemistry Catalysis Organic chemistry

Metrics

Cited By

0.00

FWCI (Field Weighted Citation Impact)

Refs

0.01

Citation Normalized Percentile

Is in top 1%

Is in top 10%

Citation History

Topics

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Coordination Chemistry and Organometallics

Physical Sciences → Chemistry → Organic Chemistry

Metal complexes synthesis and properties

Health Sciences → Medicine → Oncology

Bis(μ-pyridinyl-1-oxide)-1κO¹:2κC²;1κC²:2κO¹-bis[(η⁴-cycloocta-1,5-diene)rhodium(I)]

Abstract

Metrics

Citation History

Topics

Related Documents

Triaqua-1κO,2κ² O-bis(2,2′-bipyridine)-1κ² N,N′;2κ² N,N′-chlorido-1κCl-μ-terephthalato-1:2κ² O ¹:O ⁴-dicopper(II) nitrate monohydrate

Tetraaqua-1κO,2κ³O-(μ-2,4-dinitrophenolato-1κ²O¹,O²:2κO¹)(2,4-dinitrophenolato-1κ²O¹,O²)dilithium(I): a dinuclear lithium(I) complex

Bis(μ-2-fluorobenzoato-1:2κ²O:O′)(2-fluorobenzoato-1κ²O,O′)(2-fluorobenzoato-2κO)dinicotinamide-1κN¹,2κN¹-dizinc(II)–2-fluorobenzoic acid (1/1)

Tetrakis(μ-naphthalene-1-acetato-1:2κ²O:O′)bis(naphthalene-1-acetato)-1κ²O,O′;2κ²O,O′-bis(1,10-phenanthroline)-1κ²N,N′;2κ²N,N′-europium(III)samarium(III)

Diaqua-2κ²O-bis(μ-1-oxido-2-naphthoato)-1:2κ³O¹,O²:O^2′;2:3κ³O²:O¹,O^2′-bis(1-oxido-2-naphthoato)-1κ¹O²,O²;3κ²O¹,O²-hexapyridine-1κ²N,2κ²N,3κ²N-trimanganese(II/III) pyridine disolvate dihydrate

Bis(μ-pyridinyl-1-oxide)-1κO1:2κC2;1κC2:2κO1-bis[(η4-cycloocta-1,5-diene)rhodium(I)]

Abstract

Metrics

Citation History

Topics

Related Documents

Triaqua-1κO,2κ2 O-bis(2,2′-bipyridine)-1κ2 N,N′;2κ2 N,N′-chlorido-1κCl-μ-terephthalato-1:2κ2 O 1:O 4-dicopper(II) nitrate monohydrate

Tetraaqua-1κO,2κ3O-(μ-2,4-dinitrophenolato-1κ2O1,O2:2κO1)(2,4-dinitrophenolato-1κ2O1,O2)dilithium(I): a dinuclear lithium(I) complex

Bis(μ-2-fluorobenzoato-1:2κ2O:O′)(2-fluorobenzoato-1κ2O,O′)(2-fluorobenzoato-2κO)dinicotinamide-1κN1,2κN1-dizinc(II)–2-fluorobenzoic acid (1/1)

Tetrakis(μ-naphthalene-1-acetato-1:2κ2O:O′)bis(naphthalene-1-acetato)-1κ2O,O′;2κ2O,O′-bis(1,10-phenanthroline)-1κ2N,N′;2κ2N,N′-europium(III)samarium(III)

Diaqua-2κ2O-bis(μ-1-oxido-2-naphthoato)-1:2κ3O1,O2:O2′;2:3κ3O2:O1,O2′-bis(1-oxido-2-naphthoato)-1κ1O2,O2;3κ2O1,O2-hexapyridine-1κ2N,2κ2N,3κ2N-trimanganese(II/III) pyridine disolvate dihydrate

Bis(μ-pyridinyl-1-oxide)-1κO¹:2κC²;1κC²:2κO¹-bis[(η⁴-cycloocta-1,5-diene)rhodium(I)]

Triaqua-1κO,2κ² O-bis(2,2′-bipyridine)-1κ² N,N′;2κ² N,N′-chlorido-1κCl-μ-terephthalato-1:2κ² O ¹:O ⁴-dicopper(II) nitrate monohydrate

Tetraaqua-1κO,2κ³O-(μ-2,4-dinitrophenolato-1κ²O¹,O²:2κO¹)(2,4-dinitrophenolato-1κ²O¹,O²)dilithium(I): a dinuclear lithium(I) complex

Bis(μ-2-fluorobenzoato-1:2κ²O:O′)(2-fluorobenzoato-1κ²O,O′)(2-fluorobenzoato-2κO)dinicotinamide-1κN¹,2κN¹-dizinc(II)–2-fluorobenzoic acid (1/1)

Tetrakis(μ-naphthalene-1-acetato-1:2κ²O:O′)bis(naphthalene-1-acetato)-1κ²O,O′;2κ²O,O′-bis(1,10-phenanthroline)-1κ²N,N′;2κ²N,N′-europium(III)samarium(III)

Diaqua-2κ²O-bis(μ-1-oxido-2-naphthoato)-1:2κ³O¹,O²:O^2′;2:3κ³O²:O¹,O^2′-bis(1-oxido-2-naphthoato)-1κ¹O²,O²;3κ²O¹,O²-hexapyridine-1κ²N,2κ²N,3κ²N-trimanganese(II/III) pyridine disolvate dihydrate