Tetracarbonyl-1κ2C,3κ2C-bis[1,3(η5)-cyclopentadienyl]dihydroxido-2κ2O-diirontin(2Fe—Sn) monohydrate

Stefanie Kössel; Christoph Wagner; Kurt Merzweiler

doi:10.1107/s1600536810021975

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Tetracarbonyl-1κ²C,3κ²C-bis[1,3(η⁵)-cyclopentadienyl]dihydroxido-2κ²O-diirontin(2Fe—Sn) monohydrate

Stefanie Kössel Christoph Wagner Kurt Merzweiler

Year: 2010 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 66 (7)Pages: m811-m811 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536810021975

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Abstract

In the title hydrate, [Fe(2)Sn(C(5)H(5))(2)(OH)(2)(CO)(4)]·H(2)O, the central Sn atom is tetra-hedrally coordinated by two {Cp(CO)(2)Fe} fragments and two hydroxide groups. The [{Cp(CO)(2)Fe}(2)Sn(OH)(2)] and water mol-ecules are linked by O-H⋯O hydrogen bridges, giving two-dimensional arrays with 4.8(2) topology that stack along the c axis.

Keywords:

Cyclopentadienyl complex Chemistry Hydrate Hydroxide Medicinal chemistry Atom (system on chip) Crystallography Inorganic chemistry Organic chemistry Catalysis

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Crystal structures of chemical compounds

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Tetracarbonyl-1κ²C,3κ²C-bis[1,3(η⁵)-cyclopentadienyl]dihydroxido-2κ²O-diirontin(2Fe—Sn) monohydrate

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