[Na7UIVO2(UVO)2(UV/VIO2)2Si4O16]: A Mixed‐Valence Uranium Silicate

Cheng‐Shiuan Lee; Chia‐Hui Lin; Sue‐Lein Wang; Kwang‐Hwa Lii

doi:10.1002/anie.201001095

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[Na₇U^IVO₂(U^VO)₂(U^V/VIO₂)₂Si₄O₁₆]: A Mixed‐Valence Uranium Silicate

Cheng‐Shiuan Lee Chia‐Hui Lin Sue‐Lein Wang Kwang‐Hwa Lii

Year: 2010 Journal: Angewandte Chemie International Edition Vol: 49 (25)Pages: 4254-4256 Publisher: Wiley

DOI: 10.1002/anie.201001095

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Abstract

For U′r eyes only: A mixed-valence uranium silicate containing three different valence states of uranium has been synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains uranium silicate sheets with uranophane anion topology that are connected by UO6 octahedra to form a 2D layered structure with Na+ ions within and between the layers.

Keywords:

Uranium Valence (chemistry) Octahedron Ion Silicate Crystallography Crystal structure Hydrothermal circulation Analytical Chemistry (journal) Chemistry Materials science Physics Nuclear physics Geology

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Radioactive element chemistry and processing

Physical Sciences → Chemistry → Inorganic Chemistry

Nuclear materials and radiation effects

Physical Sciences → Materials Science → Materials Chemistry

Crystal Structures and Properties

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

[Na₇U^IVO₂(U^VO)₂(U^V/VIO₂)₂Si₄O₁₆]: A Mixed‐Valence Uranium Silicate

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[Na₇U^IVO₂(U^VO)₂(U^V/VIO₂)₂Si₄O₁₆]: A Mixed‐Valence Uranium Silicate

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[Na7UIVO2(UVO)2(UV/VIO2)2Si4O16]: A Mixed‐Valence Uranium Silicate

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