ChemInform Abstract: Mixed‐Valence Uranium Germanate and Silicate: Csx(UVO)(UIV/VO)2 (Ge2O7)2 (x = 3.18) and Cs4(UVO)(UIV/VO)2 (Si2O7)2.

Chun‐Liang Chen; Quang Bac Nguyen; Chih‐Shan Chen; Kwang‐Hwa Lii

doi:10.1002/chin.201239013

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ChemInform Abstract: Mixed‐Valence Uranium Germanate and Silicate: Cs_x(U^VO)(U^IV/VO)₂ (Ge₂O₇)₂ (x = 3.18) and Cs₄(U^VO)(U^IV/VO)₂ (Si₂O₇)₂.

Chun‐Liang Chen Quang Bac Nguyen Chih‐Shan Chen Kwang‐Hwa Lii

Year: 2012 Journal: ChemInform Vol: 43 (39) Publisher: Wiley

DOI: 10.1002/chin.201239013

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Abstract

Abstract Cs 3.18 (U 3 O 3 ) (Ge 2 O 7 ) 2 (I) is hydrothermally synthesized from an aqueous mixture of UO 3 , Cs(OH), GeO 2 , and Al in a molar ratio of Cs:U:Ge:Al = 10:1:8:0.5 (autoclave, 165 MPa, 600 °C, 2 d, 62% yield).

Keywords:

Chemistry Germanate Valence (chemistry) Uranium Analytical Chemistry (journal) Silicate Aqueous solution Nuclear chemistry Crystallography Physical chemistry Ion Physics Nuclear physics

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Radioactive element chemistry and processing

Physical Sciences → Chemistry → Inorganic Chemistry

Nuclear materials and radiation effects

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ChemInform Abstract: Mixed‐Valence Uranium Germanate and Silicate: Cs_x(U^VO)(U^IV/VO)₂ (Ge₂O₇)₂ (x = 3.18) and Cs₄(U^VO)(U^IV/VO)₂ (Si₂O₇)₂.

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