Bis(μ-3-nitrophthalato-κ2O1:O2)bis[aqua(2,2′-bipyridine-κ2N,N′)copper(II)] dihydrate

Yinfeng Han; Cheng Chen; Seik Weng Ng

doi:10.1107/s1600536810043229

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Bis(μ-3-nitrophthalato-κ²O¹:O²)bis[aqua(2,2′-bipyridine-κ²N,N′)copper(II)] dihydrate

Yinfeng Han Cheng Chen Seik Weng Ng

Year: 2010 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 66 (11)Pages: m1484-m1484 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536810043229

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Abstract

Two 3-nitro-phthalate dianions bridge two water-coordinated 2,2'-bipyridine-chelated Cu(II) atoms about a center of inversion to generate the title dinuclear compound, [Cu(2)(C(8)H(3)NO(6))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O. The geometry of the Cu(II) atom is a distorted square pyramid. Adjacent mol-ecules are linked through the coordinated and solvent water mol-ecules to form a linear ribbon running along the a axis of the monoclinic unit cell.

Keywords:

Chemistry Square pyramid Crystallography Bipyridine Ribbon Monoclinic crystal system 2,2'-Bipyridine Center (category theory) Solvent Stereochemistry Crystal structure Materials science

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Crystal structures of chemical compounds

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Bis(μ-3-nitrophthalato-κ²O¹:O²)bis[aqua(2,2′-bipyridine-κ²N,N′)copper(II)] dihydrate

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