Bis(μ-3-carboxy-2-oxidobenzoato)-κ3O1,O2:O3;κ3O3:O1,O2-bis[aqua(2,2′-bipyridine-κ2N,N′)copper(II)]

Jing Gao; Baoyong Zhu; Deliang Cui

doi:10.1107/s1600536808039913

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Bis(μ-3-carboxy-2-oxidobenzoato)-κ³O¹,O²:O³;κ³O³:O¹,O²-bis[aqua(2,2′-bipyridine-κ²N,N′)copper(II)]

Jing Gao Baoyong Zhu Deliang Cui

Year: 2008 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 65 (1)Pages: m4-m5 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536808039913

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Abstract

In the centrosymmetric dinuclear complex, [Cu(2)(C(8)H(4)O(5))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Cu(II) ion is coordinated by two N atoms from a bipyridine ligand, three O atoms from two 3-carb-oxy-2-oxidobenzoate dianions and the O atom of the water mol-ecule in a distorted octa-hedral geometry. The Cu--O(H) coordination [2.931 (3) Å] is very weak. In the crystal structure, the dinuclear units are linked into a two-dimensional network parallel to (010) by O-H⋯O hydrogen bonds.

Keywords:

Crystallography Chemistry Ligand (biochemistry) Ion Crystal structure Atom (system on chip) Hydrogen bond Molecule

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Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Metal-Organic Frameworks: Synthesis and Applications

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Bis(μ-3-carboxy-2-oxidobenzoato)-κ³O¹,O²:O³;κ³O³:O¹,O²-bis[aqua(2,2′-bipyridine-κ²N,N′)copper(II)]

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