Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)]

Chunhua Dong; Dahai Zhang; Ning Ren; XI Gai-qing; Juanjuan Hao

doi:10.1107/s1600536810052001

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Bis(μ-3,5-dinitrobenzoato-κ²O¹:O^1′)bis(μ-3,5-dinitrobenzoato)-κ³O¹,O^1′:O¹;κ³O¹:O¹,O^1′-bis[(3,5-dinitrobenzoato-κ²O¹,O^1′)(1,10-phenanthroline-κ²N,N)dysprosium(III)]

Chunhua Dong Dahai Zhang Ning Ren XI Gai-qing Juanjuan Hao

Year: 2010 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 67 (1)Pages: m102-m102 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536810052001

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Abstract

In the binuclear title complex, [Dy(2)(C(7)H(3)N(2)O(6))(6)(C(12)H(8)N(2))(2)], the Dy(III) ions exhibit a distorted monocapped square-anti-prismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating, bidentate chelating-bridging and tridentate chelating-bridging. The center of the mol-ecule is located on a crystallographic center of inversion.

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Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Lanthanide and Transition Metal Complexes

Physical Sciences → Materials Science → Materials Chemistry

Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Bis(μ-3,5-dinitrobenzoato-κ²O¹:O^1′)bis(μ-3,5-dinitrobenzoato)-κ³O¹,O^1′:O¹;κ³O¹:O¹,O^1′-bis[(3,5-dinitrobenzoato-κ²O¹,O^1′)(1,10-phenanthroline-κ²N,N)dysprosium(III)]

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