Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ8O1,O2:O2,O3;O3,O2:O2,O1-bis[triaqua(2-carboxy-3-nitrobenzoato-κ2O,O′)lanthanum(III)] dihydrate

Li-Qin Xiong; Chuan-Min Qi

doi:10.1107/s0108270106047822

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Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ⁸O¹,O²:O²,O³;O³,O²:O²,O¹-bis[triaqua(2-carboxy-3-nitrobenzoato-κ²O,O′)lanthanum(III)] dihydrate

Li-Qin Xiong Chuan-Min Qi

Year: 2006 Journal: Acta Crystallographica Section C Crystal Structure Communications Vol: 63 (1)Pages: m10-m12 Publisher: Wiley

DOI: 10.1107/s0108270106047822

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Abstract

The title compound, [La2(C8H3NO6)2(C8H4NO6)2(H2O)6].2H2O, consists of dimeric units related by an inversion center. The two La(III) atoms are linked by two bridging bidentate carboxylate groups and two monodentate carboxylate groups. Each La(III) atom is nine-coordinated by six O atoms from five different carboxylate groups and three from water molecules. Hydrogen bonds between the water molecules and between the solvent water and a carboxylate O atom are observed in the structure. In the crystal packing, there are slipped pi-pi stacking interactions between the parallel benzene rings. Both hydrogen-bonding and pi-pi interactions combine to stabilize the three-dimensional supramolecular network.

Keywords:

Hydrogen bond Crystallography Chemistry Denticity Crystal structure Nitrobenzene Stacking Molecule Stereochemistry

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Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Lanthanide and Transition Metal Complexes

Physical Sciences → Materials Science → Materials Chemistry

Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ⁸O¹,O²:O²,O³;O³,O²:O²,O¹-bis[triaqua(2-carboxy-3-nitrobenzoato-κ²O,O′)lanthanum(III)] dihydrate

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