A Trisilyl Zincate Containing Bidentate\n[(Me<sub>3</sub>Si)<sub>2</sub>Si(CH<sub>2</sub>)<sub>2</sub>Si(SiMe<sub>3</sub>)<sub>2</sub>]<sup>2-</sup> Ligands
Jaime B. Woods (2674069)Xianghua Yu (2302027)Tianniu Chen (2323696)Zi-Ling Xue (1414108)
Abstract
The trisilyl dimeric zincate [K(18-crown-6)]<sub>2</sub>{[(Me<sub>3</sub>Si)<sub>2</sub>Si(CH<sub>2</sub>)<sub>2</sub>Si(SiMe<sub>3</sub>)<sub>2</sub>]<sub>2</sub>Zn<sub>2</sub>[μ-(Me<sub>3</sub>Si)<sub>2</sub>Si(CH<sub>2</sub>)<sub>2</sub>Si(SiMe<sub>3</sub>)<sub>2</sub>]} (<b>1</b>) is reported. In the structure of <b>1</b>, each Zn\ncenter is bonded by one bridging disilyl ligand and one\nchelating disilyl ligand.
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