Carbonyl(η<sup>5</sup>-cyclopentadienyl)(trimethylsilyl isocyanide)(triphenylphosphine)iron(II) trifluoromethanesulfonate dichloromethane hemisolvate

Hiroshi Nakazawa; Masumi Itazaki; Mari Owaribe

doi:10.1107/s1600536805015308

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Carbonyl(η⁵-cyclopentadienyl)(trimethylsilyl isocyanide)(triphenylphosphine)iron(II) trifluoromethanesulfonate dichloromethane hemisolvate

Hiroshi Nakazawa Masumi Itazaki Mari Owaribe

Year: 2005 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 61 (6)Pages: m1172-m1173 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536805015308

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Abstract

In the title compound, [Fe(C5H5)(C4H9NSi)(C18H15P)(CO)](CF3SO3)·0.5CH2Cl2, the FeII atom is coordinated by carbonyl, triphenylphosphine, trimethylsilyl isocyanide and cyclopentadienyl ligands in a typical piano-stool structure. The Fe—C—N—Si arrangement is almost linear and the Fe—C, C—N and N—Si bond distances are 1.836 (3), 1.162 (4) and 1.792 (3) Å, respectively.

Keywords:

Isocyanide Trifluoromethanesulfonate Cyclopentadienyl complex Triphenylphosphine Chemistry Phosphine Trimethylsilyl Dichloromethane Medicinal chemistry Silylation Organic chemistry

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Carbonyl(η⁵-cyclopentadienyl)(trimethylsilyl isocyanide)(triphenylphosphine)iron(II) trifluoromethanesulfonate dichloromethane hemisolvate

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