JOURNAL ARTICLE

Dicarbonyl(η5-cyclopentadienyl)(trimethylsilyl isocyanide)iron(II) trifluoromethanesulfonate

Hiroshi NakazawaMasumi ItazakiMari Owaribe

Year: 2005 Journal:   Acta Crystallographica Section E Structure Reports Online Vol: 61 (6)Pages: m1073-m1074   Publisher: International Union of Crystallography

Abstract

In the title compound, [Fe(C5H5)(C4H9NSi)(CO)2](CF3SO3), the Fe atom is coordinated by two carbonyl groups, a tri­methyl­silyl­isocyanide ligand and a cyclo­penta­dienyl ligand in a typical piano-stool structure. The Fe—CN, C≡N and CN—Si bond distances are 1.862 (4), 1.157 (6) and 1.794 (4) Å, respectively, and the Fe—C—N—Si arrangement is almost linear.

Keywords:
Isocyanide Cyclopentadienyl complex Trifluoromethanesulfonate Trimethylsilyl Ligand (biochemistry) Chemistry Medicinal chemistry Silylation Crystallography Stereochemistry Organic chemistry Receptor

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Citation History

Topics

Organometallic Complex Synthesis and Catalysis
Physical Sciences →  Chemistry →  Organic Chemistry
Fluorine in Organic Chemistry
Life Sciences →  Pharmacology, Toxicology and Pharmaceutics →  Pharmaceutical Science
Magnetism in coordination complexes
Physical Sciences →  Materials Science →  Electronic, Optical and Magnetic Materials

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