(Diethylenetriamine-κ3N)(η5-pentamethylcyclopentadienyl)iridium(III) bis(trifluoromethanesulfonate)

M.A. Scharwitz; T. Van Almsick; William S. Sheldrick

doi:10.1107/s1600536807002036

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(Diethylenetriamine-κ³N)(η⁵-pentamethylcyclopentadienyl)iridium(III) bis(trifluoromethanesulfonate)

M.A. Scharwitz T. Van Almsick William S. Sheldrick

Year: 2007 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 63 (2)Pages: m537-m539 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536807002036

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Abstract

The title compound, [Ir(η5-C5Me5)(dien-κ3N)](CF3SO3)2 (dien is diethylenetriamine) or [Ir(C10H15)(C4H13N3)](CF3SO3)2, contains a half-sandwich (η5-C5Me5)IrIII fragment coordinated in a facial manner by the N atoms of a dien ligand. N—H⋯O hydrogen bonds to the trifluoromethanesulfonate counter-anions link the organometallic cations into a chiral polymeric network.

Keywords:

Iridium Trifluoromethanesulfonate Chemistry Medicinal chemistry Ligand (biochemistry) Sulfonate Hydrogen bond Organometallic chemistry Group 2 organometallic chemistry Methane sulfonate Diethylenetriamine Stereochemistry Crystallography Crystal structure Molecule Catalysis Organic chemistry Sodium

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Topics

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Coordination Chemistry and Organometallics

Physical Sciences → Chemistry → Organic Chemistry

(Diethylenetriamine-κ³N)(η⁵-pentamethylcyclopentadienyl)iridium(III) bis(trifluoromethanesulfonate)

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