(<i>S</i>-Methylcysteinato)(η<sup>5</sup>-pentamethylcyclopentadienyl)iridium(III) trifluoromethanesulfonate hemihydrate

M.A. Scharwitz; T. Van Almsick; William S. Sheldrick

doi:10.1107/s1600536806053360

ScienceGate Book Chapters

JOURNAL ARTICLE

(S-Methylcysteinato)(η⁵-pentamethylcyclopentadienyl)iridium(III) trifluoromethanesulfonate hemihydrate

M.A. Scharwitz T. Van Almsick William S. Sheldrick

Year: 2006 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 63 (1)Pages: m230-m232 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536806053360

Get Full-Text PDF Get Analytical Report

Abstract

The cation of the title compound, [Ir(C10H15)(C4H8NO2S)](CF3SO3)·0.5H2O, contains a half-sandwich [Ir(C5Me5)]2+ fragment, the IrIII atom of which is coordinated by the tridentate S-methylcysteinate ligand (S-MecysO) in a κ3N,O,S manner. An RIr configuration is observed for the transition metal and an SS configuration for the chiral thioether S atom.

Keywords:

Iridium Trifluoromethanesulfonate Chemistry Medicinal chemistry Ligand (biochemistry) Thio- Atom (system on chip) Ether Hemihydrate Stereochemistry Crystallography Catalysis Materials science Organic chemistry

Metrics

Cited By

0.20

FWCI (Field Weighted Citation Impact)

Refs

0.56

Citation Normalized Percentile

Is in top 1%

Is in top 10%

Citation History

Topics

Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Metal complexes synthesis and properties

Health Sciences → Medicine → Oncology

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

(S-Methylcysteinato)(η⁵-pentamethylcyclopentadienyl)iridium(III) trifluoromethanesulfonate hemihydrate

Abstract

Metrics

Citation History

Topics

Related Documents

Carbonyl(diethyldithiocarbamato)(η⁵-pentamethylcyclopentadienyl)iridium(III) trifluoromethanesulfonate

Chlorido(ethylenediamine-κ²N)(η⁵-pentamethylcyclopentadienyl)iridium(III) trifluoromethanesulfonate

(Diethylenetriamine-κ³N)(η⁵-pentamethylcyclopentadienyl)iridium(III) bis(trifluoromethanesulfonate)

Chlorido(η⁵-pentamethylcyclopentadienyl)(1,10-phenanthroline-κ²N,N′)iridium(III) trifluoromethanesulfonate

(1,2-Dicyanoethylenedithiolato-κ²S,S′)(η⁵-pentamethylcyclopentadienyl)iridium(III)

(S-Methylcysteinato)(η5-pentamethylcyclopentadienyl)iridium(III) trifluoromethanesulfonate hemihydrate

Abstract

Metrics

Citation History

Topics

Related Documents

Carbonyl(diethyldithiocarbamato)(η5-pentamethylcyclopentadienyl)iridium(III) trifluoromethanesulfonate

Chlorido(ethylenediamine-κ2N)(η5-pentamethylcyclopentadienyl)iridium(III) trifluoromethanesulfonate

(Diethylenetriamine-κ3N)(η5-pentamethylcyclopentadienyl)iridium(III) bis(trifluoromethanesulfonate)

Chlorido(η5-pentamethylcyclopentadienyl)(1,10-phenanthroline-κ2N,N′)iridium(III) trifluoromethanesulfonate

(1,2-Dicyanoethylenedithiolato-κ2S,S′)(η5-pentamethylcyclopentadienyl)iridium(III)

(S-Methylcysteinato)(η⁵-pentamethylcyclopentadienyl)iridium(III) trifluoromethanesulfonate hemihydrate

Carbonyl(diethyldithiocarbamato)(η⁵-pentamethylcyclopentadienyl)iridium(III) trifluoromethanesulfonate

Chlorido(ethylenediamine-κ²N)(η⁵-pentamethylcyclopentadienyl)iridium(III) trifluoromethanesulfonate

(Diethylenetriamine-κ³N)(η⁵-pentamethylcyclopentadienyl)iridium(III) bis(trifluoromethanesulfonate)

Chlorido(η⁵-pentamethylcyclopentadienyl)(1,10-phenanthroline-κ²N,N′)iridium(III) trifluoromethanesulfonate

(1,2-Dicyanoethylenedithiolato-κ²S,S′)(η⁵-pentamethylcyclopentadienyl)iridium(III)