Tribromo(3,5-dimethyl-2-nitrophenyl-κ2C1,O)tellurium(IV), bromo(3,5-dimethyl-2-nitrophenyl-κ2C1,O)tellurium(II) and bromo(3,5-dimethyl-2-nitrosophenyl-κ2C1,O)tellurium(II)

Prabodhika Mallikaratchy; Richard E. Norman; Frank R. Fronczek; Thomas Junk

doi:10.1107/s0108270103017955

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Tribromo(3,5-dimethyl-2-nitrophenyl-κ²C¹,O)tellurium(IV), bromo(3,5-dimethyl-2-nitrophenyl-κ²C¹,O)tellurium(II) and bromo(3,5-dimethyl-2-nitrosophenyl-κ²C¹,O)tellurium(II)

Prabodhika Mallikaratchy Richard E. Norman Frank R. Fronczek Thomas Junk

Year: 2003 Journal: Acta Crystallographica Section C Crystal Structure Communications Vol: 59 (10)Pages: o571-o574 Publisher: Wiley

DOI: 10.1107/s0108270103017955

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Abstract

All three title compounds, prepared from bis(3,5-dimethyl-2-nitrophenyl)ditellurium, exhibit high degrees of intramolecular Te-O coordination. Their Te-O distances increase in the order C(8)H(8)BrNOTe < C(8)H(8)BrNO(2)Te < C(8)H(8)Br(3)NO(2)Te, with distances of 2.165 (3), 2.306 (1) and 2.423 (6) A, respectively, indicating that C(8)H(8)BrNOTe may be more aptly described as 1-bromo-4,6-dimethyl-2,1,3-benzoxatellurazole.

Keywords:

Tellurium Intramolecular force Chemistry Medicinal chemistry Stereochemistry Organic chemistry

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Organoselenium and organotellurium chemistry

Life Sciences → Pharmacology, Toxicology and Pharmaceutics → Toxicology

Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Organometallic Compounds Synthesis and Characterization

Physical Sciences → Chemistry → Organic Chemistry

Tribromo(3,5-dimethyl-2-nitrophenyl-κ²C¹,O)tellurium(IV), bromo(3,5-dimethyl-2-nitrophenyl-κ²C¹,O)tellurium(II) and bromo(3,5-dimethyl-2-nitrosophenyl-κ²C¹,O)tellurium(II)

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