(μ-Diazenediyldiphenyl-κ2C2,N2:κ2C2′,N1)bis[(3,5-dimethylphenyl)tellurium(II)]

Prabodhika Mallikaratchy; Richard E. Norman; Frank R. Fronczek; Thomas Junk

doi:10.1107/s1600536805018659

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(μ-Diazenediyldiphenyl-κ²C²,N²:κ²C^2′,N¹)bis[(3,5-dimethylphenyl)tellurium(II)]

Prabodhika Mallikaratchy Richard E. Norman Frank R. Fronczek Thomas Junk

Year: 2005 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 61 (7)Pages: m1370-m1372 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536805018659

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Abstract

The title compound, C28H26N2Te2, prepared by reduction of (3,5-dimethylphenyl)(2-nitrophenyl)tellurium(II), is the first structurally characterized example of an azo group bridging two TeII centers. The compound is centrosymmetric and the Te—N distance [2.6916 (19) Å] is longer than in non-bridging azo compounds.

Keywords:

Tellurium Chemistry Crystallography Physics Inorganic chemistry

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Organoselenium and organotellurium chemistry

Life Sciences → Pharmacology, Toxicology and Pharmaceutics → Toxicology

Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Chemical Thermodynamics and Molecular Structure

Physical Sciences → Chemistry → Organic Chemistry

(μ-Diazenediyldiphenyl-κ²C²,N²:κ²C^2′,N¹)bis[(3,5-dimethylphenyl)tellurium(II)]

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