JOURNAL ARTICLE

Poly[bis(μ2-azido-κ2N1:N3)(μ2-3,5-di-2-pyridyl-1,2,4-triazole-κ4N1,N5:N2,N3)manganese(II)]

Sheng HuShu‐Hua ZhangMing‐Hua Zeng

Year: 2007 Journal:   Acta Crystallographica Section E Structure Reports Online Vol: 63 (10)Pages: m2543-m2543   Publisher: International Union of Crystallography

Abstract

In the crystal structure of the polymeric title compound, [Mn2(N3)2(C12H8N5)2]n, the MnII atom exists in an octa­hedral geometry owing to coordination by four N atoms from two 3,5-bis­(pyridin-2-yl)-1,2,4-triazolate ligands and by two azide ligands. The heterocyclic ligand binds in a chelating mode. The bidentate bridging mode of both anions leads to a linear ribbon motif.

Keywords:
Azide Chemistry Denticity Crystal structure Crystallography Chelation Ribbon Ligand (biochemistry) Atom (system on chip) Stereochemistry Materials science Inorganic chemistry

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Topics

Synthesis and Characterization of Heterocyclic Compounds
Physical Sciences →  Chemistry →  Organic Chemistry
Magnetism in coordination complexes
Physical Sciences →  Materials Science →  Electronic, Optical and Magnetic Materials
Lanthanide and Transition Metal Complexes
Physical Sciences →  Materials Science →  Materials Chemistry

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