Poly[(μ₂-azido-κ²N¹:N¹)[μ₂-5-(8-quinolyloxymethyl)tetrazolato-κ⁴N¹,O,N⁵:N⁴]manganese(II)]

Abstract

In the structure of the title compound, [Mn(C(11)H(8)N(5)O)(N(3))](n), the Mn atoms are hexa-coordinated by five N atoms and one O atom. The coordination polyhedron of the Mn atom is a slightly distorted octa-hedron. The Mn atoms are connected by azide anions with a μ(2)-1,1 mode and by 5-(8-quinolyloxymeth-yl)tetra-zolate ligands in a μ(2)-η(1)(N),η(3)-(N,N,O) fashion to form a two-dimensional framework parallel to the (100) plane. Geometric parameters of the organic ligand are in the normal ranges and the dihedral angle between the quinoline ring system and the tetra-zole unit is 7.41 (15)°. The structure involves intra- and inter-molecular C-H⋯N hydrogen bonds.