JOURNAL ARTICLE
ChemInform Abstract: A Highly Enantioselective Hydrogenation of Silyl Enol Ethers Catalyzed by Chiral Frustrated Lewis Pairs.
Year: 2015 Journal: ChemInform Vol: 46 (12) Publisher: Wiley
Abstract
Abstract Highly enantioselective metal‐free hydrogenation of silyl enol ethers is achieved by combining P(tBu) 3 with a chiral borane generated in situ by hydroboration of an axial‐chiral diene with HB(C 6 F 5 ) 2 as a frustrated Lewis pair catalyst.
Keywords:
Chemistry Hydroboration Enantioselective synthesis Enol Silylation Borane Frustrated Lewis pair Catalysis Lewis acids and bases Diene Boranes Silyl enol ether Organic chemistry Medicinal chemistry Boron
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Topics
Organoboron and organosilicon chemistry
Physical Sciences → Chemistry → Organic Chemistry
Asymmetric Hydrogenation and Catalysis
Physical Sciences → Chemistry → Inorganic Chemistry
Organometallic Complex Synthesis and Catalysis
Physical Sciences → Chemistry → Organic Chemistry
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