ChemInform Abstract: Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2‐Dicarbonyl Compounds.

Xiaoyu Ren; Haifeng Du

doi:10.1002/chin.201629048

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ChemInform Abstract: Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2‐Dicarbonyl Compounds.

Xiaoyu Ren Haifeng Du

Year: 2016 Journal: ChemInform Vol: 47 (29) Publisher: Wiley

DOI: 10.1002/chin.201629048

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Abstract

Abstract A variety of optically active α‐hydroxy ketones and esters is prepared utilizing the combination of tricyclohexylphosphine and chiral alkenylborane generated in situ from diyne as frustrated Lewis pair catalyst.

Keywords:

Chemistry Enantioselective synthesis Frustrated Lewis pair Catalysis Tricyclohexylphosphine Lewis acids and bases Optically active Organic chemistry Combinatorial chemistry

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Organoboron and organosilicon chemistry

Physical Sciences → Chemistry → Organic Chemistry

Asymmetric Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Coordination Chemistry and Organometallics

Physical Sciences → Chemistry → Organic Chemistry

ChemInform Abstract: Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2‐Dicarbonyl Compounds.

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