Gold(<scp>ii</scp>) in redox-switchable gold(<scp>i</scp>) catalysis

Philipp Veit; Carla Volkert; Christoph Förster; Vadim Ksenofontov; Steffen Schlicher; Matthias Bauer; Katja Heinze

doi:10.3204/pubdb-2020-00929

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Gold(ii) in redox-switchable gold(i) catalysis

Philipp Veit Carla Volkert Christoph Förster Vadim Ksenofontov Steffen Schlicher Matthias Bauer Katja Heinze

Year: 2019 Journal: Chemical Communications Vol: 55 (32)Pages: 4615-4618 Publisher: Royal Society of Chemistry

DOI: 10.3204/pubdb-2020-00929

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Abstract

Gold(ii) species catalyse the cyclisation of N(2-propyn-1-yl)benzamide to 2-phenyl-5-vinylidene-2-oxazoline without halide abstraction while the neutral gold(i) complex is inactive indicating a gold(ii/i) redox-switch.

Keywords:

Redox Catalysis Chemistry Combinatorial chemistry Organic chemistry

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Catalytic Alkyne Reactions

Physical Sciences → Chemistry → Organic Chemistry

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Asymmetric Hydrogenation and Catalysis

Physical Sciences → Chemistry → Inorganic Chemistry

Gold(ii) in redox-switchable gold(i) catalysis

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