Triple the fun: tris(ferrocenyl)arene-based gold(<scp>i</scp>) complexes for redox-switchable catalysis

Axel Straube; Peter Coburger; Luis Dütsch; Evamarie Hey‐Hawkins

doi:10.3929/ethz-b-000448261

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Triple the fun: tris(ferrocenyl)arene-based gold(i) complexes for redox-switchable catalysis

Axel Straube Peter Coburger Luis Dütsch Evamarie Hey‐Hawkins

Year: 2020 Journal: Chemical Science Vol: 11 (39)Pages: 10657-10668 Publisher: Royal Society of Chemistry

DOI: 10.3929/ethz-b-000448261

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Abstract

Trinuclear gold(i) complexes ofC₃-symmetric tris(ferrocenyl)arene-based tris-phosphanes with four accessible oxidation states catalyse the ring-closing isomerisation ofN-(2-propyn-1-yl)benzamide with different rates depending on their redox state.

Keywords:

Tris Redox Chemistry Isomerization Catalysis Medicinal chemistry Oxidation state Stereochemistry Photochemistry Organic chemistry

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Catalytic Alkyne Reactions

Physical Sciences → Chemistry → Organic Chemistry

Asymmetric Hydrogenation and Catalysis

Physical Sciences → Chemistry → Inorganic Chemistry

Catalytic C–H Functionalization Methods

Physical Sciences → Chemistry → Organic Chemistry

Triple the fun: tris(ferrocenyl)arene-based gold(i) complexes for redox-switchable catalysis

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