μ-Oxalato-κ4O1,O2:O1′,O2′-bis[aqua(diethylenetriamine-κ3N)nickel(II)] bis(tetraphenylborate)

Lorena M. Callejo; Iñaki Muga; Pablo Vitoria; Santiago Reinoso; P. Román; Juan M. Gutiérrez‐Zorrilla

doi:10.1107/s1600536803016362

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μ-Oxalato-κ⁴O¹,O²:O^1′,O^2′-bis[aqua(diethylenetriamine-κ³N)nickel(II)] bis(tetraphenylborate)

Lorena M. Callejo Iñaki Muga Pablo Vitoria Santiago Reinoso P. Román Juan M. Gutiérrez‐Zorrilla

Year: 2003 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 59 (8)Pages: m684-m686 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536803016362

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Abstract

The title compound, [Ni2(C2O4)(C4H13N3)2(H2O)2][B(C6H5)4]2, contains a centrosymmetric dinuclear oxalato–nickel(II) complex cation in which the oxalate ligand bridges the Ni atoms in a bis-bidentate fashion. The distorted octahedral environment of each Ni atom is completed by the three N atoms of the diethylenetriamine ligand in a fac arrangement, and by one O atom from a water molecule. Tetraphenylborate acts as the counter-anion. The crystal structure shows alternate cationic and anionic layers packed along the [10\overline 1] direction.

Keywords:

Octahedron Crystallography Ligand (biochemistry) Chemistry Oxalate Cationic polymerization Ion Denticity Crystal structure Atom (system on chip) Nickel Diethylenetriamine Inorganic chemistry

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μ-Oxalato-κ⁴O¹,O²:O^1′,O^2′-bis[aqua(diethylenetriamine-κ³N)nickel(II)] bis(tetraphenylborate)

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