Bis(dicyclohexylammonium) μ-oxalato-κ4O1,O2:O1′,O2′-bis[aqua(oxalato-κ2O1,O2)diphenylstannate(IV)]

Ndongo Gueye; Libasse Diop; K.C. Molloy; Gabriele Kociok‐Köhn

doi:10.1107/s1600536810046738

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Bis(dicyclohexylammonium) μ-oxalato-κ⁴O¹,O²:O^1′,O^2′-bis[aqua(oxalato-κ²O¹,O²)diphenylstannate(IV)]

Ndongo Gueye Libasse Diop K.C. Molloy Gabriele Kociok‐Köhn

Year: 2010 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 66 (12)Pages: m1645-m1646 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536810046738

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Abstract

The structure of the title compound, (C(12)H(24)N)(2)[Sn(2)(C(6)H(5))(4)(C(2)O(4))(3)(H(2)O)(2)], consists of a bischelating oxalate ion, located on an inversion center, which is linked to two SnPh(2) groups. The coordination sphere of the Sn(IV) ion is completed by a monochelating oxalate anion and a water mol-ecule. The Sn(IV) atoms are thus seven-coordinated. The discrete binuclear units are further connected by hydrogen bonds, leading to a supra-molecular crystal structure. The asymmetric unit contains one half dianion and one (Cy(2)NH(2))(+) cation.

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Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Lanthanide and Transition Metal Complexes

Physical Sciences → Materials Science → Materials Chemistry

Organometallic Compounds Synthesis and Characterization

Physical Sciences → Chemistry → Organic Chemistry

Bis(dicyclohexylammonium) μ-oxalato-κ⁴O¹,O²:O^1′,O^2′-bis[aqua(oxalato-κ²O¹,O²)diphenylstannate(IV)]

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