Rhodium(<scp>i</scp>), rhodium(<scp>iii</scp>) and iridium(<scp>iii</scp>) carbaporphyrins

Venkata A. K. Adiraju; Gregory M. Ferrence; Timothy D. Lash

doi:10.1039/c6dt03093a

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JOURNAL ARTICLE

Rhodium(i), rhodium(iii) and iridium(iii) carbaporphyrins

Venkata A. K. Adiraju Gregory M. Ferrence Timothy D. Lash

Year: 2016 Journal: Dalton Transactions Vol: 45 (35)Pages: 13691-13694 Publisher: Royal Society of Chemistry

DOI: 10.1039/c6dt03093a

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Abstract

Reaction of a benzocarbaporphyrin with [Rh(CO)₂Cl]₂ or [Ir(COD)Cl]₂ gave a rhodium(i) dicarbonyl complex and rhodium(iii) or iridium(iii) organometallic derivatives.

Keywords:

Rhodium Iridium Chemistry Catalysis Organic chemistry

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Porphyrin and Phthalocyanine Chemistry

Physical Sciences → Materials Science → Materials Chemistry

Metal-Catalyzed Oxygenation Mechanisms

Physical Sciences → Chemistry → Inorganic Chemistry

Supramolecular Chemistry and Complexes

Physical Sciences → Chemistry → Organic Chemistry

Rhodium(i), rhodium(iii) and iridium(iii) carbaporphyrins

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