A New Cationic Hydrido‐Bridged Rhodium(<scp>I</scp>)‐Iridium(<scp>III</scp>) Complex

Alberto Albinati; A. Musco; Ralph Naegeli; Luigi M. Venanzi

doi:10.1002/anie.198109581

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JOURNAL ARTICLE

A New Cationic Hydrido‐Bridged Rhodium(I)‐Iridium(III) Complex

Alberto Albinati A. Musco Ralph Naegeli Luigi M. Venanzi

Year: 1981 Journal: Angewandte Chemie International Edition in English Vol: 20 (11)Pages: 958-959

DOI: 10.1002/anie.198109581

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Abstract

The new complex (1), whose dark green crystals are stable in air, contains a five-coordinate rhodium(I) and a six-coordinate irid-ium(III) with three bridging hydride ligands. (1) can be prepared by reaction of [Rh(di-phos)(MeOH)2][BF4] with mer-[IrH3(PEt3)3] and subsequent precipitation with NaBPh4.

Keywords:

Rhodium Cationic polymerization Iridium Chemistry Hydride Stereochemistry Catalysis Medicinal chemistry Polymer chemistry Organic chemistry

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Asymmetric Hydrogenation and Catalysis

Physical Sciences → Chemistry → Inorganic Chemistry

Catalytic Cross-Coupling Reactions

Physical Sciences → Chemistry → Organic Chemistry

A New Cationic Hydrido‐Bridged Rhodium(I)‐Iridium(III) Complex

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