JOURNAL ARTICLE
Selective Oxidation of Cp2MoS2 and Cp2MoS4 To Give Cp2MoS2O and Cp2MoS4O, Respectively: A Novel Thermally Induced Oxygen Migration Converting 1-Oxo-Cp2MoS4O to 2-Oxo-Cp2MoS4O
Andrzej Z. RysA.-M. LebuisAlan ShaverDavid N. Harpp
Year: 1999 Journal: Organometallics Vol: 18 (7)Pages: 1113-1115 Publisher: American Chemical Society
Abstract
Oxidation of Cp2MoSx, where x = 2, 4, with m-chloroperbenzoic acid gave Cp2MoS2O and Cp2MoS4O, respectively. In Cp2MoS4O the oxygen is attached to the 2-sulfur atom of the S4 ligand; however, an intermediate was isolated and identified as the 1-oxo isomer. It thermally rearranges via first-order kinetics with rate dependence on solvent polarity to give the final 2-oxo product.
Keywords:
Chemistry Kinetics Oxygen atom Sulfur Ligand (biochemistry) Atom (system on chip) Oxygen Solvent polarity Solvent Crystallography Stereochemistry Molecule Organic chemistry Physics
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11
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1.30
FWCI (Field Weighted Citation Impact)
9
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0.80
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Topics
Polyoxometalates: Synthesis and Applications
Physical Sciences → Materials Science → Materials Chemistry
Chemical Synthesis and Reactions
Physical Sciences → Chemistry → Organic Chemistry
Organometallic Complex Synthesis and Catalysis
Physical Sciences → Chemistry → Organic Chemistry
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