Rearrangement of Molybdocene Tetraoxotetrasulfide Cp2MoS4O4 to Give [(Cp2MoS2H)2](HSO4)2: A Novel Proton-Stabilized Molybdocene Disulfide Dimer
Andrzej Z. RysA.-M. LebuisAlan Shaver
Abstract
Cp(2)MoS(4), 1, in CH(2)Cl(2) undergoes extensive oxidation by m-CPBA at -78 degrees C to give a 1,1,4,4-tetroxide, 2 (59%). Tetraoxide 2 rearranges at room temperature to give an unusual sulfur-atom protonated molybdocene disulfide dimer [(Cp(2)MoS(2)H)(2)](HSO(4))(2), 3. Crystal data for 3 are P, a = 6.751(2) Angstroms, b = 9.865(4) Angstroms, c = 11.549(5) Angstroms, alpha = 109.95(3) degrees, beta = 96.11(3) degrees, gamma = 108.22(3) degrees, V = 666.9(4) Angstroms(3), and Z = 1. The dimer was also obtained directly when the oxidation was conducted at 0 degree C in DMF. Under basic conditions, the dimer is cleaved to give molybdocene disulfide Cp(2)MoS(2), while treatment of the latter with acid converts it to the dimer 3.
Metrics
Citation History
Topics
Related Documents
Selective Oxidation of Cp2MoS2 and Cp2MoS4 To Give Cp2MoS2O and Cp2MoS4O, Respectively: A Novel Thermally Induced Oxygen Migration Converting 1-Oxo-Cp2MoS4O to 2-Oxo-Cp2MoS4O
Andrzej Z. RysA.-M. LebuisAlan ShaverDavid N. Harpp
Insertion of SO2 into the S−S Bond of Cp2MoS2 and Cp2MoS2O To Give Molybdocene Dithiosulfate and Bis(O-alkylthiosulfates)
Andrzej Z. RysA.-M. LebuisAlan ShaverDavid N. Harpp
Crystal structures of manganese hydrogen sulfates – Mn(HSO4)2, Mn(HSO4)2 · H2O and Mn(HSO4)2(H2SO4)2
Synthese und Struktur neuer Natriumhydrogensulfate Na(H3O)(HSO4)2; Na2(HSO4)2(H2SO4) und Na(HSO4)(H2SO4)2
S. TrojanovChristian WernerErhard KemnitzH. Worzala
Synthese und Struktur von Zn(HSO4)2(H2SO4)2 und Cd(HSO4)2 / Synthesis and Structure of Zn(HSO4)2(H2SO4)2 und Cd(HSO4)2
Erhard KemnitzChristian WernerA. StieweH. WorzalaS. Trojanov