JOURNAL ARTICLE
Die Zweikernkomplexe Cp2Mn2(CO)4S2 und Cp2Mn2(CO)4Se2 + / The Binuclear Complexes Cp2Mn2(CO)4S2 and Cp2Mn2(CO)4Se2
Max HerberholdDietmar ReinerB. ZIMMER‐GASSERUlrich S. Schubert
Year: 1980 Journal: Zeitschrift für Naturforschung B Vol: 35 (10)Pages: 1281-1285 Publisher: De Gruyter
Abstract
Abstract The reactions of cyclopentadienyl dicarbonyl tetrahydrofuran manganese, CpMn(CO) 2 (OC 4 H 8 ), with either COS or COSe lead preferentially to binuclear complexes, Cp 2 Mn 2 (CO) 4 S 2 and Cp 2 Mn 2 (CO) 4 Se 2 , respectively. According to an X-ray crystallographic study, the sulfur complex is a centrosymmetric molecule containing a planar Mn-(S-S*)-Mn* unit with d(Mn-S) 216.7(4) pm, d(S-S*) 200.7(6) pm and < MnSS* 114.4(2)°.
Keywords:
Manganese Cyclopentadienyl complex Tetrahydrofuran Chemistry Sulfur Crystallography X-ray crystallography Molecule Materials science Catalysis Diffraction Physics
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Topics
Organometallic Complex Synthesis and Catalysis
Physical Sciences → Chemistry → Organic Chemistry
Metalloenzymes and iron-sulfur proteins
Physical Sciences → Energy → Renewable Energy, Sustainability and the Environment
Inorganic Chemistry and Materials
Physical Sciences → Chemistry → Inorganic Chemistry
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