Direct Electrochemical Synthesis and Characterization of Coordination Compounds of Copper(II) Chloride: Part - II
Harpreet KaurAmrita KaurKim Tae-HunPark SuMoonH RehanTsuchiya YouichiFujihara HisashiWadhawan JayDMarken FrankCompton RichardG BullSteveDevis StephenGB LyalinV A PetrosyanH SenbokuM TakahasiT FukuharaS HaraAntonio PadraresSousaJ RomeroGarcia Vazquez JoseA DuranM L CasanovaI SousaAV TripathiK BairwaD MalD B NaikY YuanJ YaoC LinY ZhangR GuJ Ledesma-GarciaL G ArriagaT ChapmanR Velazquez-CastilloL A GodinezDinesh SinghPratapOnkar SrivastavaNathJ BanaitSingh BaljitKaur HarpreetJ BanaitSingh BaljitKaur HarpreetKaur HarpreetJ BanaitSingh BaljitJ BanaitSingh BaljitKaur HarpreetKaur HarpreetKaur AmandeepSheldrickLucile ArnaudetRoland BougonBuu BanPierrette CharpinJacques IsabeyMonique LanceMartine NierlichJulien Vigner
Abstract
Coordination compounds of CuCl 2 .L (where L = 1,10-phenanthroline or 2,2'bipyridyl) have been synthesized by electrolyzing the aqueous solution of hydrochloric acid and ligand at sacrificial copper anode and inert platinum cathode.The products isolated have been characterized by elemental analysis, infrared spectral data and x -ray crystallography.Current efficiencies of both these reactions are found to be quite high.
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