Bis(μ-4-amino-3,5-dimethyl-4<i>H</i>-1,2,4-triazole)bis[diiodidozinc(II)]

Rongxian Zhang; Qiu‐Yun Chen; Xiaofei Yang; Xiangyang Wu

doi:10.1107/s160053681004852x

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Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole)bis[diiodidozinc(II)]

Rongxian Zhang Qiu‐Yun Chen Xiaofei Yang Xiangyang Wu

Year: 2010 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 67 (1)Pages: m26-m26 Publisher: International Union of Crystallography

DOI: 10.1107/s160053681004852x

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Abstract

In the title compound, [Zn(2)I(4)(C(4)H(8)N(4))(2)], the Zn(II) atom is coordinated in a distorted tetra-hedral geometry by two N atoms from the triazole rings of two 4-amino-3,5-dimethyl-4H-1,2,4-triazole (admt) ligands and two iodide ligands. Doubly bridging admt ligands connect two Zn(II) atoms, forming a centrosymmetric dimer. Weak N-H⋯I and C-H⋯I hydrogen bonds play an important role in the inter-molecular packing.

Keywords:

1,2,4-Triazole Chemistry Triazole Medicinal chemistry Stereochemistry Organic chemistry

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Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole)bis[diiodidozinc(II)]

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