JOURNAL ARTICLE

Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate

Yupeng PanDacheng LiDaqi Wang

Year: 2007 Journal:   Acta Crystallographica Section E Structure Reports Online Vol: 64 (1)Pages: m96-m97   Publisher: International Union of Crystallography

Abstract

The title complex, [Ni(2)(C(4)H(8)N(4)O(2))(6)](NO(3))(4)·2CH(4)O, contains a centrosymmetric binuclear nickel(II) complex bridged by a pair of 4-amino-3,5-bis-(hydroxy-meth-yl)-1,2,4-triazole ligands. The separation between the Ni(II) atoms is 3.962 (1) Å. The Ni atoms are in a slightly distorted octa-hedral coordination. Inter-molecular N-H⋯O, N-H⋯N and O-H⋯O hydrogen bonds connect the ligands, solvent mol-ecules and nitrate ions.

Keywords:
Hydroxymethyl Methanol 1,2,4-Triazole Chemistry Nickel Triazole Medicinal chemistry Organic chemistry

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Topics

Microbial metabolism and enzyme function
Life Sciences →  Biochemistry, Genetics and Molecular Biology →  Molecular Biology
Magnetism in coordination complexes
Physical Sciences →  Materials Science →  Electronic, Optical and Magnetic Materials
Metal-Catalyzed Oxygenation Mechanisms
Physical Sciences →  Chemistry →  Inorganic Chemistry

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