JOURNAL ARTICLE
Die Kristallstrukturen von Tetramethylarsonium- und Tetramethylstibonium-monomethyltrichloroindat (CH3)4M+CH3InCl3 - (mit M = As, Sb).
H. J. GuderW. SchwarzJohann WeidleinH. J. WidlerH.‐D. Hausen
Year: 1976 Journal: Zeitschrift für Naturforschung B Vol: 31 (9)Pages: 1185-1189 Publisher: De Gruyter
Abstract
Tetramethylarsonium-, as well as tetramethylstibonium-monomethyltrichloroindate crystallizes in the monoclinic space-group Pc with two formula units in the cell. In both structures we found isolated (CH 3 )4M + - and (CH 3 )InCl 3 - - tetrahedra (M = As, Sb), from which the anionic one in markedly distorted. The distances between these isolated tetrahedral cations and anions are not equal. The tetrahedrical cations and anions form double-layers.
Keywords:
Monoclinic crystal system Crystallography Crystal structure X-ray crystallography Tetrahedron Chemistry Space group Physics Diffraction
Metrics
20
Cited By
3.44
FWCI (Field Weighted Citation Impact)
0
Refs
0.92
Citation Normalized Percentile
Is in top 1%
Is in top 10%
Citation History
Topics
Inorganic Fluorides and Related Compounds
Physical Sciences → Chemistry → Inorganic Chemistry
Solid-state spectroscopy and crystallography
Physical Sciences → Materials Science → Materials Chemistry
Organometallic Compounds Synthesis and Characterization
Physical Sciences → Chemistry → Organic Chemistry
Related Documents
JOURNAL ARTICLE
ChemInform Abstract: Kristallstrukturen von Tetramethylarsonium‐ und Tetramethylstibonium‐monomethyltrichloroindat (CH3)4M+CH3InCl3‐ (mit M = As, Sb) (monoklin, Raumgruppe Pc, Z=2).
H. J. GuderW. SchwarzJohann WeidleinH. J. WidlerH.‐D. Hausen
Journal: Chemischer Informationsdienst Year: 1976 Vol: 7 (50)
JOURNAL ARTICLE
Die Kristallstruktur von Tetramethylstiboniumtetrachlorogallat [(CH3)4Sb]+[GaCl4]- / The Crystal Structure of Tetramethylstibonium Tetrachlorogallate [(CH3)4Sb]+[GaCl4]-
H.‐D. HausenH. BinderW. Schwarz
Journal: Zeitschrift für Naturforschung B Year: 1978 Vol: 33 (5)Pages: 567-569
JOURNAL ARTICLE
Über die Reaktionen von (CH3)4N+I-, (CH3)4 N+ICl2 -, (CH3)4N+ICl4 - und (CH3)4N+Cl- mit Trifluormethylhypochlorit CF3OCl / The Reactions of (CH3)4N+I-, ( CH3)4N+ICl2 -, (CH3)4N+ICl4 - and (CH3)4N+Cl- with Trifluoromethylhypochlorite CF3OCl
Journal: Zeitschrift für Naturforschung B Year: 1997 Vol: 52 (3)Pages: 401-404
JOURNAL ARTICLE
Über Dimethylhaloniumsalze – CH3ClCH3 +MF6-, CH3BrCH3 +MF6-, CH3ICH3 +MF6 - – und Dimethylmethylendiiodoniumsalze CH3ICH2ICH3 2+(MF6-)2 (M = As, Sb) / On Dimethylhalonium Salts – CH3ClCH3 +MF6-, CH3BrCH3 +MF6-, CH3ICH3 +MF6 - – and Dimethylmethylendiiodonium Salts CH3ICH2ICH3 2+(MF6-)2 (M = As, Sb)
Journal: Zeitschrift für Naturforschung B Year: 1991 Vol: 46 (5)Pages: 561-565
JOURNAL ARTICLE
Schwingungsspektroskopische Untersuchungen an Trimethylphosphonium‐Kationen (CH3)3PX+ (X = H, D) und Kristallstrukturen von (CH3)3PD+SbCl6− und (CH3)3PCl+SbCl6−
Rolf MinkwitzG. MedgerH. Preut
Journal: Zeitschrift für anorganische und allgemeine Chemie Year: 1992 Vol: 614 (8)Pages: 102-108