Über die Reaktionen von (CH₃)₄N⁺I^-, (CH₃)_{4 N⁺ICl2 ^-, (CH3)4N⁺ICl4 ^- und (CH3)4N⁺Cl^- mit Trifluormethylhypochlorit CF3OCl / The Reactions of (CH3)4N⁺I^-, ( CH3)4N⁺ICl2 ^-, (CH3)4N⁺ICl4 ^- and (CH3)4N+Cl^- with Trifluoromethylhypochlorite CF3OCl}

Abstract

Abstract The fluorinating properties of CF 3 OCl have been demonstrated by the reactions with different iodate salts like (CH 3 ) 4 N + I - , (CH 3 ) 4 N + ICl 2 - and (CH 3 ) 4 N + ICl 4 - . At -70°C all reactions give hexafluoroiodate(V ) salts IF 6 - . In contrast, the reaction of CF 3 OCl with (CH 3 ) 4 N + Cl + yields (CH 3 ) 4 N + OCF 3 - . The products have been characterized by vibrational and NMR spectra.