A molecular pinwheel multicopper(<scp>i</scp>) cluster, [(LS−)6CuI13(S2−)2]3+with μ4-sulfido, μ3-thiolato and nitrogenligands

Yunho Lee; Amy A. Sarjeant; Kenneth D. Karlin

doi:10.1039/b513768c

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A molecular pinwheel multicopper(i) cluster, [(L^S−)₆Cu^I₁₃(S²⁻)₂]³⁺with μ₄-sulfido, μ₃-thiolato and nitrogenligands

Yunho Lee Amy A. Sarjeant Kenneth D. Karlin

Year: 2005 Journal: Chemical Communications Pages: 621-623 Publisher: Royal Society of Chemistry

DOI: 10.1039/b513768c

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Abstract

A copper(I) complex with new N2S thiol ligand transforms to a multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ (1); its X-ray structure exhibiting mu4-sulfido and mu3-thiolato coordination is presented and compared to other cuprous thiolato/sulfido clusters including that observed in the copper enzyme nitrous oxide reductase.

Keywords:

Cluster (spacecraft) Copper Chemistry Ligand (biochemistry) Multicopper oxidase Crystallography Stereochemistry Physics Enzyme Organic chemistry Computer science

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A molecular pinwheel multicopper(i) cluster, [(L^S−)₆Cu^I₁₃(S²⁻)₂]³⁺with μ₄-sulfido, μ₃-thiolato and nitrogenligands

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