[U3(μ3‐Cl)2(μ2‐Cl)3(μ1,η2‐AlCl4)3(η6‐C6Me6)3][AlCl4]—A Trinuclear Arene Complex of U<scp>III</scp>

F. Albert Cotton; Willi Schwotzer; Charles Q. Simpson

doi:10.1002/anie.198606371

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[U₃(μ³‐Cl)₂(μ²‐Cl)₃(μ¹,η²‐AlCl₄)₃(η⁶‐C₆Me₆)₃][AlCl₄]—A Trinuclear Arene Complex of U^III

F. Albert Cotton Willi Schwotzer Charles Q. Simpson

Year: 1986 Journal: Angewandte Chemie International Edition in English Vol: 25 (7)Pages: 637-639

DOI: 10.1002/anie.198606371

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Abstract

Donor‐acceptor complexes of f‐block elements with neutral π‐ligands are few in number. It has now been possible to synthesize the trinuclear U III ‐title complex from UCl 4 , AlCl 3 , C 6 Me 6 and aluminum by a modified Friedel‐Crafts reaction. Each U atom is coordinated in a pentagonal bipyramidal fashion by six Cl atoms and C 6 Me 6 .

Keywords:

Crystallography Pentagonal bipyramidal molecular geometry Chemistry Physics Crystal structure

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Coordination Chemistry and Organometallics

Physical Sciences → Chemistry → Organic Chemistry

Synthesis and characterization of novel inorganic/organometallic compounds

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[U₃(μ³‐Cl)₂(μ²‐Cl)₃(μ¹,η²‐AlCl₄)₃(η⁶‐C₆Me₆)₃][AlCl₄]—A Trinuclear Arene Complex of U^III

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[U3(μ3‐Cl)2(μ2‐Cl)3(μ1,η2‐AlCl4)3(η6‐C6Me6)3][AlCl4]—A Trinuclear Arene Complex of UIII

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