Synthesis of Mixed-Valence Platinum Triangulo Clusters\n[Pt<sub>3</sub>(μ-PPh<sub>2</sub>)<sub>2</sub>(μ-C<sub>6</sub>F<sub>5</sub>)(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>2</sub>R)<sub>2</sub>] (R = Ph, Me, Et).\nCrystal Structures of [Pt<sub>3</sub>(μ-PPh<sub>2</sub>)<sub>2</sub>(μ-C<sub>6</sub>F<sub>5</sub>)(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>3</sub>)<sub>2</sub>]\nand [Pt<sub>3</sub>(μ-AgOClO<sub>3</sub>)(μ-PPh<sub>2</sub>)<sub>2</sub>(μ-C<sub>6</sub>F<sub>5</sub>)(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>3</sub>)<sub>2</sub>]<sup>†</sup>
Larry R. Falvello (546330)Juan Forniés (2440423)Consuelo Fortuño (2539663)Fernando Durán (5234540)Antonio Martín (133724)
Abstract
The reaction between [(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>Pt(μ-PPh<sub>2</sub>)<sub>2</sub>Pt(PPh<sub>2</sub>R)<sub>2</sub>] and [Pt(C<sub>7</sub>H<sub>10</sub>)<sub>3</sub>] in toluene yields\nthe triangulo complexes [Pt<sub>3</sub>(μ-PPh<sub>2</sub>)<sub>2</sub>(μ-C<sub>6</sub>F<sub>5</sub>)(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>2</sub>R)<sub>2</sub>] (R = Ph <b>4</b>, Me <b>5</b>, Et <b>6</b>), which\ncontain two phosphido and one pentafluophenyl bridging ligands and two phosphines and\none pentafluophenyl terminal ones. The triangulo metal core displays three Pt−Pt bonds,\nas expected for a 42 valence electron count cluster. The basicity of these metal cores is\ndemonstrated through the reaction of one of the complexes (R = Ph) with AgClO<sub>4</sub> or [Ag(OClO<sub>3</sub>)(PPh<sub>3</sub>)], which gives the corresponding adduct [Pt<sub>3</sub>(AgOClO<sub>3</sub>)(μ-PPh<sub>2</sub>)<sub>2</sub>(μ-C<sub>6</sub>F<sub>5</sub>)(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>3</sub>)<sub>2</sub>] (<b>7</b>) or [Pt<sub>3</sub>Ag(μ-PPh<sub>2</sub>)<sub>2</sub>(μ-C<sub>6</sub>F<sub>5</sub>)(C<sub>6</sub>F<sub>5</sub>)(PPh<sub>3</sub>)<sub>3</sub>][ClO<sub>4</sub>] (<b>8</b>). The X-ray structures of <b>4</b> and\n<b>7</b> have been determined.
Metrics
Topics
Related Documents
Synthesis and Reactivity\nof the Unsaturated Trinuclear Phosphanido Complex [(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>Pt(μ-PPh<sub>2</sub>)<sub>2</sub>Pt(μ-PPh<sub>2</sub>)<sub>2</sub>Pt(PPh<sub>3</sub>)]
Juan Forniés (1607296)Consuelo Fortuño (1584784)Susana Ibáñez (1607290)Antonio Martín (1607293)Piero Mastrorilli (1572352)Vito Gallo (1572403)Athanassios Tsipis (1991299)
Synthesis of Neutral and Anionic Tetranuclear Clusters\n[Pt<sub>4</sub>(μ<sub>2</sub>-PPh<sub>2</sub>)<sub>3</sub>{μ<sub>3</sub>-PPh(1,2-η<sup>2</sup>-Ph)-κ<sup>3</sup><i>P</i>}(C<sub>6</sub>F<sub>5</sub>)<sub>4</sub>L] and\n[NBu<sub>4</sub>][Pt<sub>4</sub>(μ<sub>2</sub>-PPh<sub>2</sub>)<sub>3</sub>{μ<sub>3</sub>-PPh(1,2-η<sup>2</sup>-Ph)-κ<sup>3</sup><i>P</i>}(C<sub>6</sub>F<sub>5</sub>)<sub>5</sub>]\nContaining Five Coordinate P Atoms and Two Pt−Pt\nBonds<sup>§</sup>
Ester Alonso (2355991)Juan Forniés (2440423)Consuelo Fortuño (2539663)Antonio Martín (133724)A. Guy Orpen (1287909)
From B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> to B(OC<sub>6</sub>F<sub>5</sub>)<sub>3</sub>: Synthesis of (C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>BOC<sub>6</sub>F<sub>5</sub>\nand C<sub>6</sub>F<sub>5</sub>B(OC<sub>6</sub>F<sub>5</sub>)<sub>2</sub> and Their Relative Lewis Acidity
George J. P. Britovsek (1338111)Juri Ugolotti (2393140)Andrew J. P. White (1310940)
Xenon(IV)–Carbon Bond of [C<sub>6</sub>F<sub>5</sub>XeF<sub>2</sub>]<sup>+</sup>; Structural Characterization\nand Bonding of [C<sub>6</sub>F<sub>5</sub>XeF<sub>2</sub>][BF<sub>4</sub>], [C<sub>6</sub>F<sub>5</sub>XeF<sub>2</sub>][BF<sub>4</sub>]·2HF, and [C<sub>6</sub>F<sub>5</sub>XeF<sub>2</sub>][BF<sub>4</sub>]·<i>n</i>NCCH <sub>3</sub> (<i>n</i> = 1, 2); and the Fluorinating Properties of [C<sub>6</sub>F<sub>5</sub>XeF<sub>2</sub>][BF<sub>4</sub>]
Karsten Koppe (2126239)Jamie Haner (1831111)Hélène P. A. Mercier (2126242)Hermann-J. Frohn (2126236)Gary J. Schrobilgen (1505116)
New Class of Ruthenium Sulfide Clusters: Ru<sub>4</sub>S<sub>6</sub>(PPh<sub>3</sub>)<sub>4</sub>, Ru<sub>5</sub>S<sub>6</sub>(PPh<sub>3</sub>)<sub>5</sub>,\nand Ru<sub>6</sub>S<sub>8</sub>(PPh<sub>3</sub>)<sub>6</sub>
Amanda L. Eckermann (1597717)Markus Wunder (2278189)Dieter Fenske (2275519)Thomas B. Rauchfuss (1308867)Scott R. Wilson (2190925)