Zinc Germanates Incorporating Organic Amine Ligands: Solvothermal Synthesis and Structural Characterization of Zn<sub>2</sub>Ge<sub>4</sub>O<sub>10</sub>(NH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>NH<sub>2</sub>) and ZnGe<sub>2</sub>O<sub>5</sub>(NH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>NH<sub>2</sub>)
Chih-Min Wang (1825012)Chia-Hui Lin (155580)Ciao-Wei Yang (2252272)Kwang-Hwa Lii (1661773)
Abstract
Two zinc germanates incorporating bidentate-bridging organic amine ligands have been synthesized under solvothermal conditions by using the amines as solvents. Their structural features are infinite chains formed of edge-sharing ZnO<sub>4</sub>N trigonal bipyramids and unbranched vierer single layers with the composition [Ge<sub>4</sub>O<sub>10</sub>] and discrete ZnO<sub>2</sub>N<sub>2</sub> tetrahedra and unbranched zweier double chains with the composition [Ge<sub>2</sub>O<sub>5</sub>], respectively.
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