JOURNAL ARTICLE

Heteroleptic Dipyrrin/Bipyridine Complexes of Ruthenium(II)

Serena J. Smalley (2399632)Mark R. Waterland (1480213)Shane G. Telfer (1441561)

Year: 2016 Journal:   OPAL (Open@LaTrobe) (La Trobe University)   Publisher: La Trobe University

Abstract

The synthesis and characterization of a series of heteroleptic dipyrrinato/2,2′-bipyridine complexes of ruthenium(II) are reported. Spectroscopic analysis, including resonance Raman, indicates that the complexes are only weakly emissive and that the dipyrrin and Ru → bipyridine (metal-to-ligand charge transfer) chromophores are uncoupled.

Keywords:
Chromophore Characterization (materials science) Resonance (particle physics) Electron paramagnetic resonance Bipyridine Series (stratigraphy) Chemical solution

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Physical Sciences →  Materials Science →  Materials Chemistry
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Physical Sciences →  Chemistry →  Organic Chemistry
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