JOURNAL ARTICLE

Heteroleptic Dipyrrin/Bipyridine Complexes of Ruthenium(II)

S.J. SmalleyMark R. WaterlandShane G. Telfer

Year: 2008 Journal:   Inorganic Chemistry Vol: 48 (1)Pages: 13-15   Publisher: American Chemical Society

Abstract

The synthesis and characterization of a series of heteroleptic dipyrrinato/2,2'-bipyridine complexes of ruthenium(II) are reported. Spectroscopic analysis, including resonance Raman, indicates that the complexes are only weakly emissive and that the dipyrrin and Ru --> bipyridine (metal-to-ligand charge transfer) chromophores are uncoupled.

Keywords:
Chemistry Ruthenium Chromophore Bipyridine 2,2'-Bipyridine Ligand (biochemistry) Raman spectroscopy Photochemistry Polymer chemistry Stereochemistry Crystallography Organic chemistry Crystal structure Receptor Catalysis

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Topics

Luminescence and Fluorescent Materials
Physical Sciences →  Materials Science →  Materials Chemistry
Molecular Sensors and Ion Detection
Physical Sciences →  Chemistry →  Spectroscopy
Porphyrin and Phthalocyanine Chemistry
Physical Sciences →  Materials Science →  Materials Chemistry
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