Rational Synthesis of A<sub>2</sub>B-type <i>meso</i>-Triarylsubporphyrins
Takayuki Tanaka (35719)Masaaki Kitano (1475446)Shin-ya Hayashi (2078653)Naoki Aratani (1420036)Atsuhiro Osuka (1393408)
Abstract
Rational synthesis of A<sub>2</sub>B-type <i>meso</i>-arylsubporphyrins has been accomplished by the condensation of triethylamine–tri-<i>N</i>-tripyrromethene–borane with acid chlorides. These subporphyrins are useful for evaluations of the intrinsic substituent effects and the influences of substitution patterns, A<sub>3</sub>-type versus A<sub>2</sub>B-type substitution.
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