<i>meso</i>-Pyrimidinyl-Substituted A<sub>2</sub>B- and A<sub>3</sub>-Corroles
Thien H. Ngo (1785133)Francesco Nastasi (2249329)Fausto Puntoriero (1678195)Sebastiano Campagna (1678210)Wim Dehaen (496141)Wouter Maes (536942)
Abstract
A variety of <i>meso</i>-pyrimidinyl-substituted A<sub>2</sub>B- and A<sub>3</sub>-corroles (A = 4,6-dichloropyrimidin-5-yl) have been synthesized by careful optimization of the macrocyclization conditions. <i>meso</i>-Pyrimidinylcorroles offer the distinct advantage of an unprecedented broad scope of functionalization options. Highly sterically encumbered triarylcorroles were readily prepared via efficient nucleophilic aromatic substitution and Suzuki cross-coupling procedures.
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