Stabilized α-Helix-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones

Masanobu Nagano (1742932); Mitsunobu Doi (1537876); Masaaki Kurihara (1407931); Hiroshi Suemune (1547716); Masakazu Tanaka (493432)

JOURNAL ARTICLE

Stabilized α-Helix-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones

Masanobu Nagano (1742932)Mitsunobu Doi (1537876)Masaaki Kurihara (1407931)Hiroshi Suemune (1547716)Masakazu Tanaka (493432)

Year: 2016 Journal: OPAL (Open@LaTrobe) (La Trobe University) Publisher: La Trobe University

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Abstract

Chiral cyclic α-amino acid containing oligopeptide catalyzed highly enantioselective epoxidation of α,β-unsaturated ketones and the α-helical secondary structure of the peptide catalyst were revealed by X-ray crystallographic analysis.

Keywords:

Enantioselective synthesis Catalysis Oligopeptide Peptide Epoxide Amino acid

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Organic Chemistry Cycloaddition Reactions

Physical Sciences → Chemistry → Organic Chemistry

Polyoxometalates: Synthesis and Applications

Physical Sciences → Materials Science → Materials Chemistry

Asymmetric Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Stabilized α-Helix-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones

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