Stabilized α-Helix-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones

Masanobu Nagano; Mitsunobu Doi; Masaaki Kurihara; Hiroshi Suemune; Masakazu Tanaka

doi:10.1021/ol101435w

ScienceGate Book Chapters

JOURNAL ARTICLE

Stabilized α-Helix-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones

Masanobu Nagano Mitsunobu Doi Masaaki Kurihara Hiroshi Suemune Masakazu Tanaka

Year: 2010 Journal: Organic Letters Vol: 12 (15)Pages: 3564-3566 Publisher: American Chemical Society

DOI: 10.1021/ol101435w

Get Full-Text PDF Get Analytical Report

Abstract

Chiral cyclic alpha-amino acid containing oligopeptide catalyzed highly enantioselective epoxidation of alpha,beta-unsaturated ketones and the alpha-helical secondary structure of the peptide catalyst were revealed by X-ray crystallographic analysis.

Keywords:

Chemistry Enantioselective synthesis Catalysis Helix (gastropod) Stereochemistry Combinatorial chemistry Organic chemistry

Metrics

Cited By

4.30

FWCI (Field Weighted Citation Impact)

Refs

0.94

Citation Normalized Percentile

Is in top 1%

Is in top 10%

Citation History

Topics

Organic Chemistry Cycloaddition Reactions

Physical Sciences → Chemistry → Organic Chemistry

Polyoxometalates: Synthesis and Applications

Physical Sciences → Materials Science → Materials Chemistry

Chemical Synthesis and Analysis

Life Sciences → Biochemistry, Genetics and Molecular Biology → Molecular Biology

Stabilized α-Helix-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones

Abstract

Metrics

Citation History

Topics

Related Documents

Stabilized α-Helix-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones

ChemInform Abstract: Stabilized α‐Helix‐Catalyzed Enantioselective Epoxidation of α,β‐Unsaturated Ketones.

Lanthanides-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones

Ytterbium-Catalyzed Epoxidation of α,β-Unsaturated Ketones

Highly Enantioselective Epoxidation of α,β‐Unsaturated Ketones Catalyzed by Primary‐Secondary Diamines