Tetrakis(μ-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′,κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)praseodymium(III)]

Jin-Bei Shen; Jialu Liu; Guoliang Zhao

doi:10.1107/s1600536811034702

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Tetrakis(μ-2-phenoxypropionato)-κ³O,O′:O′;κ³O:O,O′,κ⁴O:O′-bis[(1,10-phenanthroline-κ²N,N′)(2-phenoxypropionato-κ²O,O′)praseodymium(III)]

Jin-Bei Shen Jialu Liu Guoliang Zhao

Year: 2011 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 67 (9)Pages: m1321-m1321 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536811034702

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Abstract

In the centrosymmetric binuclear title complex, [Pr(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Pr(III) ions are linked by four 2-phen-oxy-propionate (L) groups through their bi- and tridentate bridging modes. Each Pr(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate carboxyl-ate group and four bridging carboxyl-ate groups in a distorted PrN(2)O(7) monocapped square-anti-prismatic geometry. The title compound is isotypic with its terbium- and dysprosium-containing analogues.

Keywords:

Chemistry Terbium Dysprosium Denticity Crystallography Ion Propionate Carboxylate Stereochemistry Crystal structure Inorganic chemistry

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Tetrakis(μ-2-phenoxypropionato)-κ³O,O′:O′;κ³O:O,O′,κ⁴O:O′-bis[(1,10-phenanthroline-κ²N,N′)(2-phenoxypropionato-κ²O,O′)praseodymium(III)]

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Tetrakis(μ-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′,κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)dysprosium(III)]

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