Tetrakis(μ2-2-phenoxypropionato)-κ3O,O′:O′;κ3O:O,O′;κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(2-phenoxypropionato-κ2O,O′)lanthanum(III)]

Jin-Bei Shen; Jialu Liu; Guoliang Zhao

doi:10.1107/s1600536811036117

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Tetrakis(μ₂-2-phenoxypropionato)-κ³O,O′:O′;κ³O:O,O′;κ⁴O:O′-bis[(1,10-phenanthroline-κ²N,N′)(2-phenoxypropionato-κ²O,O′)lanthanum(III)]

Jin-Bei Shen Jialu Liu Guoliang Zhao

Year: 2011 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 67 (10)Pages: m1358-m1358 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536811036117

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Abstract

In the centrosymmetric binuclear title complex, [La(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two La(III) ions are linked by four 2-phen-oxy-propionate (L) groups in bi- and tridentate bridging modes. Each La(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate chelating carboxyl-ate group and four bridging carboxyl-ate groups in a distorted LaN(2)O(7) monocapped square-anti-prismatic geometry.

Keywords:

Denticity Chemistry Crystallography Ion Chelation Propionate Bridging (networking) Group (periodic table) Bioinformatics Stereochemistry Crystal structure Inorganic chemistry Computer science

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Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Lanthanide and Transition Metal Complexes

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Tetrakis(μ₂-2-phenoxypropionato)-κ³O,O′:O′;κ³O:O,O′;κ⁴O:O′-bis[(1,10-phenanthroline-κ²N,N′)(2-phenoxypropionato-κ²O,O′)lanthanum(III)]

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