Synthesis of (n⁵-R¹C₅H₄)(CO)₂Mo(n²-S₂R) via Reaction of (μ-RS)(μ-p-MeC₆H₄SO₂S)Fe₂(CO)₆ with Nucleophiles (n⁵-R¹C₅H₄)(CO)₃MoSeNa. Crystal Structure of (n⁵-MeO₂CC₅H₄)(CO)₂Mo(n²-S₂Bu^t)

Abstract

The reaction of (μ-RS)(μ- p-MeC 6 H 4 SO 2 S)Fe 2 (CO) 6 with ( n 5 -R 1 C 5 H 4 )(CO) 3 MoSeNa gave organomolybdenum complexes ( n 5 -R 1 C 5 H 4 )(CO) 2 Mo( n 2 -S 2 R) (3a R = Et, R 1 = H; 3b R = Bu t , R 1 = MeO 2 C), the structure of 3b being determined by X-ray diffraction analysis.