JOURNAL ARTICLE
Thermal Transformation of cis- and trans-[{Mo(CO)3H}2{μ-η5:η5-C5H3(SiMe2)2C5H3}] into [{Mo(CO)3}2{μ-η5:η5-C5H4(SiMe2SiMe2)- C5H4}](Mo−Mo) Promoted by Hydride Migration
Francisco AmorErnesto de JesúsPascual RoyoAmelio Vázquez de Miguel
Year: 1996 Journal: Inorganic Chemistry Vol: 35 (11)Pages: 3440-3441 Publisher: American Chemical Society
Abstract
When cis- or trans-[{Mo(CO)3H}2{μ-η5:η5-C5H3(SiMe2)2C5H3}] (1) is heated for 5 days to 90 °C in toluene or C6D6, the unexpected complex [{Mo(CO)3}2{μ-η5:η5-C5H4(SiMe2SiMe2)C5H4}] (2) is obtained, in which the hydride has migrated to the cyclopentadienyl group and the two silicon atoms have been coupled. The formation of 2 has been studied by labeling techniques.
Keywords:
Chemistry Cyclopentadienyl complex Toluene Hydride Silicon Crystallography Metal Analytical Chemistry (journal) Catalysis Organic chemistry
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Citation History
Topics
Organometallic Complex Synthesis and Catalysis
Physical Sciences → Chemistry → Organic Chemistry
Asymmetric Hydrogenation and Catalysis
Physical Sciences → Chemistry → Inorganic Chemistry
Organoboron and organosilicon chemistry
Physical Sciences → Chemistry → Organic Chemistry
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