Intercalation of Alkali Metal Cations into Layered Organotitanium Oxides

José Gracia; Avelino Martı́n; Miguel Mena; M.Del C. Morales-Varela; Josep M. Poblet; Cristina Santamarı́a

doi:10.1002/ange.200390215

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Intercalation of Alkali Metal Cations into Layered Organotitanium Oxides

José Gracia Avelino Martı́n Miguel Mena M.Del C. Morales-Varela Josep M. Poblet Cristina Santamarı́a

Year: 2003 Journal: Angewandte Chemie Vol: 115 (8)Pages: 957-960 Publisher: Wiley

DOI: 10.1002/ange.200390215

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Abstract

Deprotonierung des Komplexes [{Ti(η5-C5Me5)(μ-O)}3(μ3-CH)] mit Alkalimetallalkylen und -amiden erwies sich als zuverlässige Methode zur Intercalierung von Alkalimetallionen zwischen metallorganische Titanoxidschichten (siehe Bild). Der Intercalierungsprozess und die erhaltenen Strukturen wurden anhand von DFT-Rechnungen analysiert.

Keywords:

Intercalation (chemistry) Alkali metal Chemistry Metal Inorganic chemistry Crystallography Organic chemistry

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Coordination Chemistry and Organometallics

Physical Sciences → Chemistry → Organic Chemistry

Intercalation of Alkali Metal Cations into Layered Organotitanium Oxides

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